Causes of High Chloride Ion Content in Silica Fume
Core Causes: Raw Materials and Production Process
1. Impure Raw Materials (Primary Cause)
The core raw materials for smelting are quartzite (silica stone) and carbonaceous reducing agents (e.g., petroleum coke, coal, wood chips).
If these materials contain chloride impurities—for instance, quartzite sourced from coastal areas, saline-alkali lands, or ancient seabeds may adsorb chloride salts; reducing agents such as petroleum coke may also contain chlorine from their formation process—these chlorides (e.g., NaCl, KCl) will volatilize or decompose at temperatures exceeding 2000°C in the electric arc furnace.
The volatilized chlorine will enter the dust collection system along with the flue gas, eventually condensing and adhering to the surface of
silica fume particles, resulting in excessive chloride ion content in the finished silica fume.
2. Accidental Contamination During Processing
Electrodes: Certain types of graphite electrodes may contain trace amounts of chlorine.
Cooling system leakage: If the cooling water system of the smelting furnace leaks, and the cooling water is chlorinated (e.g., disinfected with sodium hypochlorite), the chloride-containing water will vaporize instantly upon entering the high-temperature zone, carrying chloride ions into the flue gas.
Environmental factors: For smelters located in coastal regions, air rich in salt (NaCl) may be drawn into the workshop’s ventilation or dust collection systems, contaminating the silica fume.
3. Efficient Capture by the Dust Collection System
Silica fume is recovered from flue gas using large-scale baghouse dust collectors. This system acts like a highly efficient "filter," capturing all volatile substances in the flue gas indiscriminately. If chlorine is introduced from raw materials or processing, the dust collector will collect these chlorides as well, concentrating them in the final silica fume product.
